It is well-known that there are two ways to entangle three qubits (https://arxiv.org/abs/quant-ph/0005115) and nine ways to entangle four qubits (https://arxiv.org/abs/quant-ph/0109033).
I found in a paper (page 22 left column of https://arxiv.org/abs/2101.02431) that there are infinitely many ways to entangle five qubits, but I am not sure how to see or prove this or if this is correct.