To get started on this problem, here is a general observation for any $n$:
You can only measure intervals of time of the form
$$\frac{m}{2^n}\cdot 1\mbox{h}$$
where $m$ and $n$ are non-negative integers.
Proof (using the extremal principle):
Suppose there was a number of ropes you could use to measure an interval which is not of the proposed form above. Take the minimum number of ropes $n$ for which this is possible, then $n≥2$ (as for $n=1$ it is not possible as shown in the question).
There must be a way of lighting the $n$ ropes so that the interval $\ t = t_2-t_1$ between two "distinct times"1 $\ t_1$ and $t_2$, where $t_1<t_2$, cannot be described by the above form. As $t_2>0$, there must be a rope $r$ that has completely burned down (otherwise, $t_2$ would not be a distinct time - see the footnote). Due to $t_1<t_2$, you can measure $t_1$ without using $r$ (so $n-1$ ropes suffice), which means that $t_1$ has the form above due to the minimal choice of $n$.
Consider the very last time $t_3$ rope $r$ is lit. By the same argument as above (you do not need $r$ to measure this time), it follows that $t_3$ has the above form. Accordingly, $\left|t_3-t_1\right|$ is also of that form. As $t = t_2-t_1 = (t_2-t_3)+(t_3-t_1)$ is by assumption not of the above form (but $\left|t_3-t_1\right|$ is), it follows that $t_2-t_3$ is not of the form above either.
However, this cannot be true:
Look at amounts of time $t_{r,1},\ldots,t_{r,l}$ that $r$ actually burns. These satisfy the relation $$n_1\cdot t_{r,1} + \ldots + n_1\cdot t_{r,l} = 1\mbox{h}$$
where $n_i = 1,2$, depending on whether $r$ burns at one or both ends. All the amounts of time $t_{r,1},\ldots,t_{r,l-1}$ are of the above form, because they are measured without using $r$. So $t_{r,l}$ also has to be of the form above. But $t_{r,l} = t_2-t_3$, which is a contradiction to the conclusion of the last paragraph.
Therefore, the assumption that there is a number of ropes which can be used to measure an amount of time not of the form above has to be wrong.
1. The start of the experiment or the time a rope has burned out, as there are no other possible events.