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0 votes
1 answer
440 views

Finite potential well and nature of its solutions

The question I have is about nature of solutions, not a solution or a specific answer that I am looking for. If we define a potential well centred at $x=0$ as the following, $$V(x) = \left\{ \begin{...
ludwigvan's user avatar
  • 131
2 votes
2 answers
1k views

Why can't energy be below the minimum of the potential in a bound state? [duplicate]

I just stumbled across the problem and have no idea how to solve it: "Considering the Time-Independent Schrodinger Equation for a stationary state $\psi$ with energy $E$, that is $$\psi '' = \...
Johnn.27's user avatar
  • 418
1 vote
0 answers
187 views

Potential energy and atomic units in the Bohr model

I have a question regarding the final sentence written in the solution to part iii) (found below) for the question given below. In the Bohr model of the hydrogen atom, the radius of the electron ...
Sirius Black's user avatar
2 votes
1 answer
156 views

Intuiting qualitatively the shapes of the eigenfunctions of a finite well-like potential, using the infinite well eigenfunctions as an inspiration

Consider, for example, the third excited state of an infinite square well: Now consider the following potential: If we wanted to sketch the rough shape of the third excited eigenfunction of this ...
Pancake_Senpai's user avatar
4 votes
2 answers
338 views

How to solve Schroedinger's equation with Kratzer potential?

Kratzer potential is defined by $$V(r)={\frac{\alpha}{r}+\frac{\beta}{r^2}}.$$ I read that the Schroedinger equation for this potential has an analytical solution in terms of hypergeometric ...
Manas Dogra's user avatar
  • 1,088
0 votes
2 answers
783 views

Classical period of Morse potential [closed]

A particle of mass $m$ and energy $E<0$ moves in a one-dimensional Morse potential: $$V(x)=V_0(e^{-2ax}-2e^{-ax}),\qquad V_0,a>0,\qquad E>-V_0.$$ From the only other question I have ...
Frost Ravenstorm's user avatar
0 votes
1 answer
1k views

Finite square well bound states

Let's suppose I have a finite potential well: $$ V(x)= \begin{cases} \infty,\quad x<0\\ 0,\quad 0<x<a\\ V_o,\quad x>a. \end{cases} $$ I solved the time-independent Schrodinger equation ...
Andrew's user avatar
  • 113
3 votes
2 answers
1k views

Perturbation theory with infinite potential

I'm trying to solve an excercise that involves first order perturbation theory and an infinite potential. To ease the problem, I tried to consider an easier one dimensional model. Consider an infinite ...
user85231's user avatar
1 vote
1 answer
184 views

The energy difference between $H$ atom and $H^+$ ion in Thomas Fermi Theory

The famous Thomas Fermi theory says that we can express the total energy of a atomic system with $N$ electrons orbiting around a charged nucleus of atomic number $Z$ in terms of radial density of ...
Swarnadeep Seth's user avatar
1 vote
1 answer
1k views

Well-defined momentum

I have a question which states: Show that a particle can have a well-defined momentum in every energy eigenstate if and only if the potential energy is uniform in space. I am completely unsure how ...
M.B.'s user avatar
  • 77
3 votes
4 answers
2k views

Meaning of transmission coefficient greater than one in a potential well problem

Consider the finite 1D wedge-shaped potential well given by $$V(x)=V_0\left(\frac{|x|}{a}-1\right) \hspace{10pt}\mathrm{for}\hspace{3pt} |x|<a;\hspace{6pt}V(x)=0 \hspace{10pt}\mathrm{for}\hspace{...
Soba noodles's user avatar
0 votes
2 answers
3k views

Particle in a finite well: Potential energy function

I'm a chemist, not a physicist, but am taking a quantum chemistry course right now and I'm having difficulty grappling with the following: For the particle in a finite potential well, so long as no ...
Brian's user avatar
  • 687
1 vote
1 answer
766 views

De Broglie wave length of electron [closed]

Consider an electron with total energy $E>V_2$ in a potential well with $$V(x)= \begin{cases} \infty & x< 0 \\ V_1 & 0< x< L \\ V_2 & x>L \end{cases} ...
sequence's user avatar
  • 568
1 vote
2 answers
3k views

Wave function for step potential

Given the step potential $$V(x)=\begin{cases} 0~~~~~~~~\text{if }~~x \leq 0 \\ V_0~~~~~~\text{if }~~x > 0 \end{cases}$$ Consider the case where $E < V_0$. In this region $x \leq 0$ we have ...
user avatar
4 votes
1 answer
6k views

Derivation of Interaction energy of Dipole - Induced Dipole Interaction

I see that the formula giving the potential (interaction) energy of a dipole and an induced dipole is $$V=-\frac{C}{r^6}$$ where $$C=\frac{\mu_1^2 \alpha'_2}{4 \pi \epsilon_0}$$ and that the formula ...
GnomeSort's user avatar
  • 345