In $k$-space the allowed values for standing waves in a cube of side length $L$ are given by
$$\vec{k} = \left(\frac{\pi}{L}\right) (n_1, n_2, n_3)$$
where the $n_i$ are nonnegative integers. Why are these numbers non-negative only?
In $k$-space the allowed values for standing waves in a cube of side length $L$ are given by
$$\vec{k} = \left(\frac{\pi}{L}\right) (n_1, n_2, n_3)$$
where the $n_i$ are nonnegative integers. Why are these numbers non-negative only?
Very good question, indeed.
At first you've made small error about wavenumber (original, not edited) definition. There can fit $n$ half-waves in a box of size $L$, so :
$$\tag 1 n = \frac{L}{\lambda /2} = \frac {2\pi L}{\pi \lambda}=\frac {kL}{\pi}$$
From (1) follows, that $$ \tag 2 k = n \frac \pi L$$
Now back to your question, why $n=0,1,2,3,\ldots$ ? Sure, mathematically you could do $-k = -n \pi/L$ to fill other spectrum part of "negative wavenumbers", BUT ... it doesn't make sense because :