This is a question from the AP Physics 2 2022 FRQ. Why does the potential energy of the atom and the kinetic energy of the electron decrease after a photon is absorbed? Shouldn't both of them increase?
1 Answer
In the answer key, especially the picture, it clearly showed that the potential energy increased.
The wording of it being
Smaller in magnitude but still negative
is a positive change.
As for why the kinetic energy decreased, that is a consequence of a detail in the calculation. You can get the correct behaviour from Virial theorem—since the magnitude of the potential energy decreased, so must the magnitude of the kinetic energy.
If you want a more physical understanding, the approximate idea is that, if you have a circular orbit of greater radius at the same angular momentum, then the orbit goes slower. This is the case even in the orbits of the planets in our Solar system. Orbits that are farther away simply has to be slower. The gravitational force gets weaker, and this is the physical interaction causing the centripetal acceleration, and so the orbits must be slower.
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$\begingroup$ Thank you! That makes a lot of sense. I realized later that you could also see that the kinetic energy decreases from the equation they make you derive earlier in the equation. $\endgroup$– FrogCommented May 24, 2023 at 22:19