The temperature variation in resistivity $\rho$ is obtained by first principles from the temperature variation in conductivity $\sigma = 1/\rho$. In a (free-electron) conductor, $\sigma$ depends on the number density of free electrons $\rho_{N,e-}$ and their mobility $\mu_{e-}$. The former is a weakly increasing function of temperature and the latter decreases approximately as inverse temperature. To first order, we approximate conductivity as being inversely dependent on temperature. In doing so, we ignore the affects from an increasing carrier density with increasing temperature and mildly non-linear variation ($\approx T^{3/2}$) for a decrease in mobility from phonon scattering as temperature increases.
This leaves us with one typical expression giving a linear dependence for resistivity versus temperature.
$$ \rho = \rho_o(1 - \alpha(T - T_o)) $$
When we want a more accurate expression for $\rho(T)$, we must return to how conductivity varies with temperature and remove the approximations. We do not expand resistivity in higher order powers of $T$.
The parameters $\rho_o$ and $\alpha$ in the above expression are dependent on two things. First, the material. Secondly, the reference temperature $T_o$.
With the above in mind, the mistake in the conjecture is to propose that $\rho_o$ and $\alpha$ should be changed when we change $T$. Alternatively put, we do not report resistivity as though we have made a calculation for a change going from one temperature to another. We report resistivity as being AT a certain temperature relative to a reference temperature.
Consider the case that $\rho_o$ and $\alpha$ are defined at 0$^o$C.
For 100$^o$C
$$\rho_{100} = \rho_o(1 - \alpha(100 - 0))$$
For 0$^o$C
$$\rho_{0} = \rho_o(1 - \alpha(0 - 0))$$
Consider the case that $\rho_o$ and $\alpha$ are defined at 100$^o$C. Use different symbols to avoid confusion.
For 100$^o$C
$$\rho_{100} = \rho_o'(1 - \alpha'(100 - 100))$$
For 0$^o$C
$$\rho_{0} = \rho_o'(1 - \alpha'(0 - 100))$$
For the above, $\rho_o \neq \rho_o'$ and $\alpha \neq \alpha'$.