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The names para- and ortho-exciton stem from the fact that -- in superficial analogy to para- and ortho-hydrogen -- the wave function that forms the electron-hole bound state can either be a singlet state with vanishing total spin or a triplet state with total spin $1$. In a semiconductor that shows strong spin-orbit interaction $S^2$ and $S_z$ are no good quantum numbers any more. Therefore the para- and ortho-exciton states can not be eigenstates of these operators.

Is it possible to still make this distinction for the exciton in the case of spin-orbit coupling? If not, is there a redefinition of how to distinguish para- and ortho-excitons?

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    $\begingroup$ In an LS-coupling scheme it would seem natural to redefine those states in terms of their total angular momentum $J=L+S$. $\endgroup$
    – Anyon
    Commented Apr 21, 2022 at 15:50

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