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In a non-degenerate semiconductor with (Ec-Ef) > 4kT separation, Maxwell-Boltzmann distribution can be used for simplification. I do not get why the term non-degenerate is used in this context? Degeneracy refers to multiple states having equal energies. Does the term degeneracy have different meanings in different contexts? Points where different bands cross are also referred to as degenerate points. At high dopings, dopants also form a band which can interact with the semiconductor bands. Is this interaction (band crossing) causing the degeneracy leading to a the term degenerate semiconductor? Can someone shed some light on this concept of degeneracy?

Thanks

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When used in reference to a semiconductor, the term "degenerate" means that it is doped so much that the material has metallic properties such as a Fermi surface and high electrical conductivity.

To be strictly correct, it is more appropiate to say that the semiconductor "has degenerate electron statistics" when said statistics are only appropiately described by a Fermi-Dirac distribution at thermal equilibrium, which is the case when the semiconductor is highly doped. However, the phrase "degenerate semiconductor" is considered acceptable shorthand for the term "semiconductor with degenerate electron statistics".

Evidently, this concept of degeneracy is different from the degeneracy of energy states, in which the term is also often used in solid-state physics. However, the degeneracy of the energy of the eigenstates of a Hamiltonian is just an instance of a broader mathematical concept of degeneracy, which applies when multiple members of a set share a common characteristic, such as the value of their energy. Off the top of my head, a classical system of coupled harmonic oscillators may have degenerate oscillation modes, sharing a common frequency. Propagating electromagnetic modes in a waveguide can be said to be degenerate if they have the same propagation constant.

The concept of degenerate electron bands, as you say, is then that of two different bands which share states with common Bloch wave vector (up to the addition of a reciprocal lattice vector) and energy. This concept is clearly different from that of the degeneracy of the electron statistics of a doped semiconductor, which, again, qualifies if Fermi-Dirac statistics are necessary to describe the occupation of electronic states in thermal equilibrium.

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  • $\begingroup$ I think the concept of degenerate electron statistics needs a little bit more explanation. I am marking the answer as accepted since it clarifies the difference. Do you have any reference that explains the origin of the term degenerate in the context of statistics? Electron statistics also deal with occupation of states (of course different in different kind of statistics...MB...FD etc.) but it seems that it might "point" towards something like degeneracy of states again. Thank you. $\endgroup$ Commented Jan 8, 2018 at 21:23

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