Any two isomorphic simplicial complexes are simple-homotopy-equivalent.
This is a fairly simple result, but it is not obvious. Yet I have been surprisingly unable to find it in the literature on discrete Morse theory (e.g., Scoville or Kozlov).
To clarify the definitions involved: Simplicial complexes are assumed to be finite by definition here. Simple-homotopy equivalence is the equivalence relation on the class of all simplicial complexes generated by elementary collapses. That is, we say that two simplicial complexes are simple-homotopy-equivalent if they can be transformed into one another via a chain of elementary collapses or expansions (the inverse of simplicial collapses). Introducing new vertices or removing ghost vertices is allowed in the process, but renaming existing vertices is not. Nevertheless, the above result says that it is possible to rename a vertex by a sequence of elementary collapses and expansions.
The proof idea is to rename vertices one by one (possibly using some "buffer elements" if a new vertex clashes with an old one). Thus, we only need to prove the following fact: If $\Delta$ is a simplicial complex, if $a$ is a vertex of $\Delta$, and if $b$ is not a vertex of $\Delta$, then the complex $\Delta\left[a\mapsto b\right]$ (obtained by replacing $a$ by $b$ in $\Delta$) is simple-homotopy-equivalent to $\Delta$. To show this fact, we introduce the larger complex $\Gamma$ whose vertices are the vertices of $\Delta$ as well as $b$, and whose faces are the faces of $\Delta$ as well as the sets $S \cup \left\{b\right\}$ and $\left(S \setminus \left\{a\right\}\right) \cup \left\{b\right\}$ for all faces $S$ of $\Delta$ that contain $a$. Now, it is easy to see that $\Gamma$ collapses onto $\Delta$ (since we can collapse the new face-pair $S \cup \left\{b\right\}$ and $\left(S \setminus \left\{a\right\}\right) \cup \left\{b\right\}$ for each $S$, starting with the highest-dimensional ones), and likewise $\Gamma$ collapses onto $\Delta\left[a\mapsto b\right]$ as well. Thus, $\Delta\left[a\mapsto b\right]$ is simple-homotopy-equivalent to $\Delta$.
But I would rather not elaborate on this argument in a paper about something else, and would much prefer to have a reference to cite. Note that I am working with simplicial complexes -- not CW complexes, nor spaces -- and it is not obvious to me that results from the other settings can be converted in any automatic way.