As hinted by user2661923, we can answer the first 2 questions as follows:
Let's say the 4 persons are $A_1, A_2, A_3$ and $A_4$, meaning that the order of drawing cards is $A_1, A_2, A_3$ and then $A_4$.
Also let's assume that we draw the cards 8 times instead of 4.
And we count only the first 4 draws.
Let's number the draws from 1 to 8.
For each draw (e.g. draw 3), each card has equal chance to be in that draw.
Therefore the unique card has a probability of $\frac{1}{8}$ to be taken in each draw.
Q1: What is the probability that one of the players will draw the unique card?
Answer: This happens when the unique card is among the first 4 cards to be drawn.
The answer is $4 \times \frac{1}{8}= \frac{1}{2}$
Q2: What is the probability that the fourth player will draw the unique card?
Answer: This happens when the unique card is in draw 4.
The answer is $\frac{1}{8}$