The isomorphism would have to map some element of $(\mathbb{Q},+)$ to $2$. There is no element of $(\mathbb{Q}_{>0},\times)$ whose square is $2$, but whatever number is mapped to $2$ has a half in $(\mathbb{Q},+)$. More generally speaking, you can divide by any natural number $n$ in $(\mathbb{Q},+)$, but you can't generally draw $n$-th roots in $(\mathbb{Q}_{>0},\times)$. More abstractly speaking, you can introduce an invertible multiplication operation on $(\mathbb{Q},+)$ to turn it into a field (in fact that in a sense is the point of the construction of $\mathbb{Q}$) but you can't define a corresponding exponentiation operation within $(\mathbb{Q}_{>0},\times)$.
The isomorphism that you expected to exist exists not between $(\mathbb{Q},+)$ and $(\mathbb{Q}_{>0},\times)$ but between $(\mathbb{Q},+)$ and $(b^\mathbb{Q},\times)$ for any $b\in\mathbb{R}_{>0} \setminus\{1\}$. Since $b^\mathbb{Q}$ always contains irrational elements, this is never a subgroup of $(\mathbb{Q}_{>0},\times)$.