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I'm looking for a way to compare the joint strength of beam-to-column connections of pre-cast and site cast concrete. Is it possible to do this on a FEA software?

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It should be possible. You will probably need to describe volumetric change during curing, which should be possible using element "swelling" feature. As a result, there will be different prestress fields. Since you have more control in case of pre-casting, I would guess it has a potential to have more advantageous residual stress field than site cast.

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