Is it possible to increase/maximise rigidity through either increasing the diameter (max 25mm) and/or making it hollow?
Yes, up to the point where the walls collapse. For a solid rod, stiffness will go up roughly as the radius raised to the fourth power -- but weight goes up as radius squared.
For constant-weight tube, stiffness will initially go up as radius to the fourth (when the hole is small), then settle out to going up as radius squared. Keep it up, and because the wall thickness has to go down with increasing radius to keep the weight down, the thing will get fragile and just plain break (squeeze a soda can for an idea of why).
I have ... acrylic ... too flexible.
Materials selection may be an issue. Unless you must choose acrylic because of its looks or other non-strength physical properties, you may want to use something that's just plain stronger. Assuming that glass is right out, you may want to investigate other plastics for this job (or ask if there's a glass that you could use -- I don't know if you could get tempered glass tubes in those dimensions).