Yes, or preferably so.
Note that the value given, is almost always winding to core (or exterior surface), not wire-to-wire. There's no way to test (hi-pot) that; it has to be done at frequency, and then real power is needed (to work against the component's impedance). It can really only be done as a matter of design, choosing wire of adequate ratings (grade of enamel).
Having been through this question before, I'm afraid I don't have much help to offer: either flip through a lot of datasheets, or ask manufacturers for comment.
As I recall, the last comments I got were "go ahead, don't worry about it". I wasn't exactly left brimming with confidence...
Though I will note, that was probably with larger inductors than you'll have, and thicker wire tends to have thicker enamel. You may have trouble getting a smaller inductor rated for as much (again, if rated at all). But it's the same problem regardless, and it's not like I've said anything concrete anyway.
If nothing else, a custom design, with tape between layers, or adequate grade of wire (TIW even), isn't terrifically painful. Seems a lot to bother for an otherwise off-the-shelf component, but, if you need design assurances, that's one way to get it.