I have an unknown system that can be modelled as a high-order RC circuit:
I performed the impedance spectroscopy measurement of it and fitted the equivalent components. Now I should calculate the time constants of the circuit, three in this case.
The \$\tau_i= R_iC_i\$ approximation doesn’t work for me.
I found some great suggestions online and on this forum but I can't answer to the problem yet.
I thought to use the parallel/series formula: $$Z=R_0+\left(R_1 \parallel \frac{1}{C_1s}\right)+\left(R_2 \parallel \frac{1}{C_2s}\right)+\left(R_3 \parallel \frac{1}{C_3s}\right)$$
Obtaining:
$$Z=R_0+\frac{R_1}{1+R_1C_1s}+\frac{R_2}{1+R_2C_2s}+\frac{R_3}{1+R_3C_3s}$$
But now I'm stuck. Should I find the roots of \$Z\$ (with MATLAB)? Are the \$1/s\$ values the time constants?
With the help of the microcap software I simulated the circuit using the values used by Verbal Kint (blue, red, green). I calculated the time required for each capacitor to reach 63.2% of the maximum voltage or V at infinite time. I also calculated the time constants considering the Thevenin circuit by eliminating the capacitors (cyan, magenta, light green).
I also noticed that the function that I wrote above has zeros for s = -610.5, -89403 and -281440. Calculating
I obtain very similar values to the other methods, but I don't know why of this result.
Finally I compared al these "time constants" with the values of a and b obtained by Verbal Kint:
At this point I am wondering which one of these results is the most correct but I guess the definition of time constant it is a bit forced. What do you think? Which one would you pick?
I repeated the same considerations made above but with a circuit having very similar components. In this case it is clear visually that the time constants should be around 0.25 ms. The results are shown in the figure. You can see that in reality with no method you get all three correct values, except the graphical method which, however, is inconvenient.