Is there any way to calculate the ESR of electrolytic capacitors for
high frequencies?
If you need a particularly low ESR then there is little option other than to choose a capacitor whose data sheet explicitly gives you this information. For instance, the B41888 range from TDK: -
![enter image description here](https://cdn.statically.io/img/i.sstatic.net/ZCRoD.png)
As with anything, you get what you pay for so, if ESR is important to your circuit then shop around for a capacitor that explicitly tells you the information unambiguously. This is what data sheets are for. Several Panasonic capacitor data sheets also specify ESR (from memory). I'm sure there will be others.
Electrolytic capacitors that don't give this invaluable information in their data sheets (or don't have links to it) are just not worth buying IMHO unless, it's not important your design.
I don't have a device to measure it
don't you have a signal generator and an oscilloscope? \$\endgroup\$