As an exercise to the reader, two lemmas:
Lemma 1. If $a, b$ are strings of symbols with a partial order, and
$\text{numinv}$ counts the number of inversions in a string of symbols then
$$\text{numinv}(ab) = \text{numinv}(a) + \text{numinv}(b) + \text{crossinv}(a, b)$$
where $$\text{crossinv}(a, b) = |\{(i,j) \in \{1,\dots,|a|\}\times\{1,\dots,|b|\} \mid a_i > b_j\}|.$$
Lemma 2. $\text{crossinv}$ has the distributive property over
concatenation, that is for strings $a, b, c$ we have
\begin{align}
\text{crossinv}(a, bc) &= \text{crossinv}(a, b) + \text{crossinv}(a, c)\\
\text{crossinv}(ab, c) &= \text{crossinv}(a, c) + \text{crossinv}(b, c).
\end{align}
You can use the above two lemmas repeatedly to generalize, and see that for a tuple of strings $(x_1, \dots, x_n)$
$$\text{numinv}(x_1x_2\dots x_n) = \sum_{i=1}^n \text{numinv}(x_i) + \sum_{i=1}^n\sum_{j=i+1}^n\text{crossinv}(x_i, x_j).$$
Since the first sum is constant for any re-ordering of $x$, we can ignore it for our problem. In fact, if we sort the symbols inside each $x_i$ you can compute $\text{crossinv}(x_i, x_j)$ in $O(|x_i| + |x_j|)$ time. So we only need to minimize the second sum by re-ordering $x$.
However, I do believe that this is a difficult problem to solve optimally. A greedy swapping approach won't work. As a counter-example (I apologize for the somewhat length counterexample, it's just one I found during experiments with randomly generated arrays) consider the following array of arrays:
$$(39, 23, 9, 31, 1, 44), (35, 41, 1, 49, 23, 38, 4, 11), (13, 10, 17, 5, 38, 50, 46), (28, 21), (45, 46, 33)$$
This has $102$ inversions when concatenated. The unique optimal concatenation order is
$$(28, 21), (39, 23, 9, 31, 1, 44), (35, 41, 1, 49, 23, 38, 4, 11), (13, 10, 17, 5, 38, 50, 46), (45, 46, 33)$$
with $100$ inversions. However this can't be generated with a simple swap. I've found similar counterexamples for single-symbol substring rotations.
A simple greedy growing approach won't work either. $(41, 3, 31), (16, 11, 47)$ is uniquely optimally ordered, but if we extend this with $(30, 20)$ the unique optimal ordering becomes
$$(16, 11, 47), (30, 20), (41, 3, 31)$$
Which is in no way a simple extension of the previous.
To go even further, Tim shows in this answer that if you view $\text{crossinv}$ as a black box function, and you don't exploit any of its special properties, then this problem is NP-complete and you're doomed to fail. So any efficient optimal algorithm must use some special property of $\text{crossinv}$.
For very large amount of arrays you will probably see the best real-world results using a non-deterministic technique such as genetic evolution to optimize the number of inversions, although this wouldn't guarantee optimality. Or perhaps I'm overestimating this problem's difficulty and someone comes along with a better answer.