All Questions
Tagged with theoretical-chemistry thermodynamics
6
questions
114
votes
1
answer
6k
views
Is there a general consensus on the causes of the alpha-effect?
There have been various explanations posited for the α-effect. The α-effect refers to a phenomenon wherein nucleophiles with lone pairs on atoms adjacent (i.e., in the α- position) to the atom bearing ...
- 11.9k
8
votes
1
answer
2k
views
Why is N₂ stable but HCN and C₂H₂ unstable?
Compounds with triple bonds generally seem to be unstable. $\ce{HCN}$ and $\ce{C2H2}$ are high-energy, relatively short-lived molecules that will readily polymerise or react with other organic ...
- 1,661
11
votes
2
answers
2k
views
How does an oscillating reaction work?
I watched a Belousov--Zhabotinsky reaction video showing an orange solution that goes to clear and then back to orange (and so forth.)
The reaction goes through a number of cycles before it will no ...
- 6,801
18
votes
1
answer
732
views
What is the relation between surface tension and initial molecular harmonic?
Initial harmonic is measured as Hartree/Bohr^2 ( like IHarmonic=n in Gaussian Software ). As I am from physics background I am used to look at features from their dimension point of view:
Actually ...
- 2,141
4
votes
1
answer
208
views
Plasma creation and condensation
Every chemical has a decomposition temperature. My understanding is that above that temperature molecular bonds are broken. And if we raise the heat high enough then all molecular bonds will break ...
- 3,340
3
votes
1
answer
2k
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Electrode potentials at interfaces?
My questions relates to the fundamental concept of electrochemistry, more specifically the electrode potentials.
1) First, why is there a potential difference at the interface of two phases? ...
- 6,795