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1 vote
0 answers
485 views

Equivalence point pH derivation of a tribasic acid

Considering $\pu{100 mL} \ \pu{0.1 M} \ \ce{H3A}$ and $\pu{0.1 M} \ \ce{NaOH}$ titration curve: I understood the half equivalence points, but couldn't understand the reason why $\mathrm{pH} = \frac{1}...
gobbledy-gook's user avatar
-1 votes
1 answer
161 views

Finding a Mistake Calculating the pH of Ammonium Acetate

I'm trying to calculate the $\mathrm{pH}$ of a $\pu{0.10 M}$ solution of ammonium acetate, and I am struggling to find what mistake I am making within the following calculations: We know that $\dfrac{[...
COsborne's user avatar
  • 102
4 votes
3 answers
253 views

Is pK_{In} = pH at equivalence point still true for weak basic organic indicators?

I am reading Ostwald Theory of Titration which says that indicators are organic weak acids or bases. To prove the relation that $\mathrm{p}K_\mathrm{In} = \mathrm{pH}$, the textbook uses the following ...
Aditya's user avatar
  • 261
3 votes
2 answers
821 views

Calculating pH of rain water

The concentration of $\ce{SO2}$ in the atmosphere over a city on a certain day is $\pu{10 ppm}$. Given that solubility of $\ce{SO2}$ in water is $\pu{1.3653 mol L-1}$ and $\mathrm{p}K_\mathrm{a}$ of $\...
Equation_Charmer's user avatar
2 votes
1 answer
3k views

Calculating molecular weight of an acid based on given values of mass, volume, pH and pKa

This is what I thought was an easy problem but according to a given answer I am doing it wrong: $\pu{11 mg}$ of a monoprotic acid was dissolved in $\pu{0.5 l}$ of water. The resulting $\mathrm{pH}$ ...
Pettersson's user avatar
2 votes
5 answers
22k views

Why does a buffer work best at the pH closest to its pKa?

I think I'm having trouble understanding exactly how the $\mathrm{p}K_\mathrm{a}$ relates here on a conceptual level. For example I know that carbonic acid works somewhat well as a buffer at $\mathrm{...
Taylor's user avatar
  • 29
2 votes
2 answers
37k views

Titration of H3PO4 with NaOH

I came across an ionic equilibrium problem stating: Find the pH when 150 ml 1 M $\ce{NaOH}$ has been added to 100 ml 1 M $\ce{H3PO4}$. I'm stuck with this question. What I know: $$\ce{H3PO4 + NaOH ...
user avatar
3 votes
2 answers
10k views

About pH of an aqueous solution of SO2

Probably we can have an aqueous solution of $\ce{SO2}$ by dissolving it in water, because we would have an equilibrium between $\ce{SO2(g)}$ and $\ce{SO2(aq)}$: $$\ce{SO2(g) <=> SO2(aq)}$$ How ...
On the way to success's user avatar