All Questions
24
questions
2
votes
1
answer
67
views
Does solubility product dictate predominant precipitate from the solution with several ionic compounds?
While removing temporary hardness through boiling, magnesium bicarbonate will give $\ce{Mg(OH)2}.$ $\ce{Mg(OH)2}$ predominates over $\ce{MgCO3}$ as the solubility product $K_\mathrm{sp}$ of $\ce{Mg(OH)...
1
vote
1
answer
157
views
Solubility of SrF2 in aqueous solution of NaF
This might be really simple question but I have no idea how to proceed to solve such kind of question.
The solubility product of $\ce{SrF2}$ in water is $\pu{8E-10}$. Calculate its solubility in 0.1M ...
2
votes
1
answer
103
views
Equilibrium Solubility of CO2 in Aqueous Solution and its Dependence on H3O+ Concentration
The equilibrium solubility of $\ce{CO2}$ in an aqueous solution is given by three chemical reactions:
$$
\begin{align}
\ce{CO2(g) &<=> CO2(aq)}\label{rxn:R1}\tag{R1}\\
\ce{CO2(aq) + H2O &...
1
vote
1
answer
105
views
What is the maximum number of silver(Ⅰ) ions in one litre of a 0.003 M sodium sulfide solution?
What is the maximum number of silver(Ⅰ) ions that can be present dissolved in one litre of a $\pu{0.003 M}$ $\ce{Na2S}$ solution?
According to my book, silver(I) reacts with sulfide producing $\ce{...
2
votes
2
answers
147
views
Find the added volume of HCl so that the ions separate
Suppose we have a 10mL solution that contains 0.02M $\ce{Ag^+}$ and 0.04M $\ce{Ba^{2+}}$. a) Find the necessary volume to be added of $\ce{HCl}$ to separate all the silver. (Assume to be separated if ...
0
votes
0
answers
126
views
Why is the Ag+ concentration in a beaker fixed in the reaction between excess AgCl (s) and KI (aq) from the start? [duplicate]
This arises as a sub-question for the following question: Calculate the concentration of I- in a solution obtained by mixing 0.10 M KI with an excess of AgCl(s).
I tried to look at How does addition ...
0
votes
2
answers
1k
views
How does addition of AgCl affect concentration of iodide in KI solution?
In a mixture of $\ce{AgCl(s)}$ and initial $\pu{0.10 M}$ $\ce{KI}$, what is the $[\ce{I-}]$ after the reaction proceeds?
Disclaimer: This is not a graded assignment, but rather a problem I'm trying to ...
2
votes
2
answers
116
views
Criterion for gravimetric analysis of silver
If the only criterion for gravimetric analysis of silver is solubility of precipitate, which one of the following two compound are we supposed to choose? $K_\mathrm{s}(\ce{AgCl}) = \pu{1.78E-10}$ and ...
0
votes
2
answers
712
views
How to calculate mass of calcium fluoride that will dissolve in sodium fluoride solution?
The solubility product of calcium fluoride, $\ce{CaF2},$ is $\pu{1.46E-10 mol^3 dm^{-9}.}$
What mass of calcium fluoride will dissolve in $\pu{500 cm^3}$ of $\pu{0.10 mol dm^{-3}}$ sodium fluoride ...
1
vote
1
answer
77
views
Seeing solubility in various cases
Match the following:
$\begin{array}{|c|c|c|c|} \hline &\textrm{Column-I}&&\textrm{Column-II} \\\hline \textrm{(A)}&\ce{AgBr}&\mathrm{(p)}&\mathrm{(Solubility~in~water~is~more~...
2
votes
1
answer
883
views
Finding the concentration of each ion in saturated solution of lead(II) hydroxide
Question
If the solubility of $\ce{Pb(OH)2}$ is $\pu{0.155 g/L},$ then the concentration of each ion in a saturated solution of $\ce{Pb(OH)2}$ is
A. $[\ce{Pb^2+}] = \pu{0.155 g/L}$ and $[\ce{OH-}] = \...
2
votes
2
answers
345
views
Calculating equilibrium concentrations of silver and halide ions
$\pu{500 ml}$ of $\pu{0.01 M}$ $\ce{AgNO3}$ is mixed with $\pu{500 ml}$ of solution containing $\pu{0.1 M}$ $\ce{NaCl}$ and $\pu{0.1 M}$ $\ce{NaBr}$. $K_\mathrm{sp}$ of $\ce{AgCl}$ is $10^{-10}$ and $...
1
vote
1
answer
170
views
Should I include ions from the solvent in solubility product constant calculations?
I'm trying to determine the Solubility Constant $K_\mathrm{sp}$ of $\ce{Ba(NO3)2}$ dissolved in nitric acid solution $\ce{HNO3}$ from experimental data.
$\ce{HNO3}$ will be mostly dissociated so ...
1
vote
2
answers
2k
views
Calculating solubility of iron(III) hydroxide in water
The following example in Skoog's Analytical Chemistry uses mass-balance and charge-balance equations to calculate the solubility of iron(III) hydroxide in aqueous solution.
$$
\begin{align}
\ce{Fe(...
4
votes
1
answer
1k
views
Finding equilibrium constant from solubility product constant
Given
$$\ce{CuI(s) <=> Cu+(aq) + I-(aq)}\, ;\qquad K_\mathrm{sp} = 1.2 \cdot 10^{-12}$$
write a reasonable chemical reaction that describes the decomposition of $\ce{CuI2}$ in aqueous ...