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Why is 10 times phosphate-buffered saline more acidic (~6.9) than 1 time phosphate-buffered saline (~7.4)? [closed]

Recently, I've been told that similar pH shift (of about 0.5 units) was observed with 20 times NPS solution as well. In case of NPS the authors provide the following recipe for the 20 times solution: ...
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