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4 votes
1 answer
95 views

Why is my Ni or Fe cathode blackening and pores getting blocked during alkaline (6 M KOH) electrolysis?

I am conducting an electrolysis process for hydrogen $(\ce{H2})$ and oxygen $(\ce{O2})$ generation using a $\pu{6 M}$ $\ce{KOH}$ alkaline solution. During the process, I have observed that my cathode ...
Bhavik Modi's user avatar
4 votes
1 answer
223 views

Do ion-exchange membranes *always* require ions to pass in both directions?

In an answer to this question, it was asserted that: Student always tend to forget that a solution must remain electrically neutral by all means. If you want a certain ion to leave water, you must ...
abligh's user avatar
  • 189
1 vote
0 answers
149 views

Green deposition on the anode after electrolysis of sodium bicarbonate solution in tap water

I use $\pu{12 V}$ battery with copper wires and tap water with $\ce{NaHCO3}$ dissolved in it. I connected the battery and everything went as expected but after 5 minutes bubbling stopped. I took out ...
Ferid9's user avatar
  • 35
3 votes
3 answers
3k views

How to separate a mixture of sodium chloride and sodium hydroxide?

I recently did a double displacement reaction in which I formed a solution of water with sodium hydroxide and sodium chloride dissolved in it. Now I want to separate both of them. How can I do this?
zuha's user avatar
  • 39
2 votes
0 answers
409 views

Effect of charge density on electrolysis of dilute sulphuric acid

I am told that if electrolysis of dilute sulfuric acid is performed under high charge density, then the following reaction takes place at anode instead of evolving oxygen: $$\ce{2 HSO4- -> H2S2O8 +...
Robin Singh's user avatar
2 votes
0 answers
150 views

Competing half reactions in electrolysis of aqueous solution of sodium hydroxide

If you run a direct current using pure nickel electrodes through a solution of NaOH in distilled water, you will separate the water into hydrogen and oxygen. Are there any other reactions that could ...
MadScientist's user avatar
2 votes
1 answer
3k views

Does electrolysis of aqueous tin(II) chloride produce Cl₂, SnCl₄ or both?

When applying a current to an aqueous solution of tin(II) chloride, tin crystals grow from the cathode. However, I'm not sure about the anode. It seems like there are two possible reactions: $$\ce{2 ...
Cheezey's user avatar
  • 123