I have a question of a more mathematical nature on the mathSE (Symmetric Direct Product Distributive?) that received a good answer, but I think an answer more oriented to chemists would be a useful resource here.
I'm trying to determine the symmetry of the second overtone band of the degenerate $\Pi_u$ bend of $\ce{CO2}$. I'm told I need to use the formula$$\chi_v(\hat{R})=\frac{1}{2}[\chi(\hat{R})\chi_{v-1}(\hat{R})+\chi(\hat{R}^v)]$$ where $v$ is the number of quanta in the mode, $\hat{R}$ is an operation and $\chi_{v}$ is the character of that operation for the $(v-1)^{\text{th}}$ overtone. I arrive at the correct answer, which is that the second overtone has symmetry $\Pi_u\oplus\Phi_u$.
But this formula seemed complicated so I wanted to see if I could get the result just from taking the symmetric direct product of the state three times like so: $$\Pi_u\otimes\Pi_u\otimes\Pi_u=(\Sigma^+_g\oplus\Delta_g)\otimes\Pi_u=2\Pi_u\oplus\Phi_u$$
Following the direct product tables I seem to get this, which has an extra $\Pi_u$.
I know this is wrong because the representation should only be quadruply degenerate, corresponding to the 4 different ways of distributing the quanta between the original degenerate modes: $(3,0) (2,1) (1,2) (0,3)$.
Why does this approach fail? Does the symmetric direct product not distribute over the direct sums?