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Why is a brine solution consisting of a small fraction of salt in water, more effective in melting ice on a surface, than just pure salt?

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    $\begingroup$ greater surface area in contact with the ice. $\endgroup$
    – MaxW
    Commented Jan 8, 2017 at 19:20

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This is because the brine solution is already in solution, whereas granular salt has to dissolve first. If ice is present instead of water, this is difficult, as there is no liquid water for the salt to dissolve in.

Secondly, salt dissolution is an endothermic process, so it will further reduce the temperature of the surroundings. For example, if you have an ice and water solution and add salt crystals you can bring the temperature of the ice/water combination to a much lower temperature (even below $\pu{-10^\circ C}$!).

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