A complex is classified as paramagnetic or diamagnetic based on the electronic configuration of the central atom/ion. Should the properties (para/dia) of surrounding ligands also affect the nature of the complex?
For example, a $\mathrm{d^6d^2sp^3}$ complex of $\ce{Fe}$ would be called diamagnetic. Will it still be called diamagnetic if one of the ligand is, let's say, paramagnetic superoxide ion ($\ce{O_2^-}$)?
$\begingroup$
$\endgroup$
1
-
$\begingroup$ A paramagetic molecule, such as O2 or NO, has one or more un-paired electrons so you can work this out for your complex. $\endgroup$– porphyrinCommented May 13 at 7:18
Add a comment
|