The expression follows (1) from the principle that ions forming due to dissociation of electrolytes are the charge carriers responsible for the conductance of electrolyte solutions, (2) from an empirical observation (Kohlrausch's law of independent migration of ions), and (3) from the definition of the limiting value of the molar conductivity as the concentration of an electrolyte as the value of the molar conductivity as the electrolyte concentration goes to zero.
The limiting conductivity of electrolytes is more than just a definition, of course, it has the important property that it is a constant, which is consistent with the independent behavior of individual ions as the electrolyte concentration goes to zero, and is therefore consistent with Kohlrausch's law.
The introduction of the degree of dissociation reflects the fact that ions are charge carriers, whereas undissociated neutral species are not. Therefore only the fraction of electrolyte that has dissociated contributes to the molar conductivity.