To add an analogy: imagine you have a friend who married a jerk, and you wonder why. After all, there are so many people in the world, nearly $10^{10}$ at the latest count! How do people decide who to pair up with? Well, in that case it might have been due to a chance encounter at a mixer at which both got slightly tipsy (and believe it or not he happened to be the nicest guy there).
The analogy is that atoms don't choose. They usually just mix randomly, sometimes slowly, sometimes at extremely high speeds. There is sometimes no chance to evaluate all possible matches, it's the first atom you encounter you end up with. At times that one is a rare catch, other times it's one like any other. And sometimes an atom dumps a weakly-bound jerk when it later meets another more attractive atom.