There are multiple similar questions already on SU but they seem to refer to increasing the bandwidth by using LAN and WLAN in parallel.
What I would like to do on Windows 7 is using WLAN for surfing and LAN for Remote Desktop in parallel. Currently I have to deactivate WLAN for using RD on LAN. The optimal solution of course would be to simply surf via LAN - sadly this is not possible.
Is it possible to configure which network access is used by what programs?