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Is there a way to which we can align them at boot up time that WAMP should
start first then skype. (Both use port 80)
Yes, you can simply not auto start Skype. Instead add a batch file to your startup folder with two commands in it. The first command would be to sleep while the WAMP stack powers up, the second command would be to start skype.
(e.g. timeout /t 30
to pause for 30 seconds).
Both use port 80
Both use port 80 by default. Both can be changed.
For a web based system your basic URL is http://host.domain.tld:80
. If you do not type either http or :80 then these will be guessed clippy style. Changing them might not be preferred (though it certainly would solve things).
For skype there is no need to specify a port. Skype can use almost any port it wishes to. It just likes to try ports 80 and 443 because those are often opened in firewalls. However it can and will work fine with any other port. And IIRC it will select there on its own.
The option to try to bind to ports 80 and 443 is merely to minimise problems for most people with a proper FW setup. It also causes enough problems for people who do more than average stuff with their computers and Skype has (or had, not sure what a version of Skype which runs on XP has) an option not to bind to these ports. This is why Skjerns answer will work.
Example file.
@echo off
echo Welcome to your new and improved Skype delayed start batch file!
echo Doing nothing for the next 10 seconds
timeout /t 10
echo Starting Skype
START C:\"Program Files (x86)"\microsoft\skype.exe
Explanations:
@echo off
is not needed, but without it all the commands will be echo'd to the screen. Echo off makes it cleaner.
echo Welcome to your new and improved Skype delayed start batch file!
Just some filler text. Not needed, but especially when trying something new it is nice get get status information.
timeout /t 10
This waits 10 seconds or until you press a key.
START C:\"Program Files (x86)"\microsoft\skype.exe
this starts a program and closes the batch file (cmd) window. Without the start
part a black box will remain open until you close skype.
Note: Adjust the path to wherever you actually installed skype. Since Skype if now bought by Microsoft I am guessing in Microsofts standard path, which is %program files%\firmname\program_name.