It's a big difference so it's somewhat surprising but the standard charger for the Dell Vostro is 90W at 19.5VDC and the battery (either the 6 or 9 cell variants) are 11.1VDC, per this spec sheet
This is the default 6 cell battery
I highly recommend you buy a Dell branded battery; either direct or from a reseller. You'll avoid the risk related to the previous link and be assured compatibility.
Reason for difference in battery vs. charger voltage:
In nearly every case the voltage (and total power rating) provided by a laptop charger will be more than what is needed to charge the battery alone, as you want the battery to be able to charge while actively using it, so the charger needs to provide enough power to do both. Typically the voltage is cut down for the charging circuit using whats called a buck converter (DC to DC step down converter) and the current flow to the battery is controlled with a PWM (pulse width modulator) which allows the charging circuit to slow or stop the charging rate based on the charge level, battery temp, etc.