I wouldn't do that if I were you. For a filesystem you should use the tools of the os for which it was created. These cross-over tools often don't work as well as you might wish.
I am gathering you only have one drive? If so, then my best suggestion, assuming your data takes up less than half the drive, is:
- using a live dvd of ubuntu, say, resize down the ext4 partition (meaning resize the filesystem in the partition)
- create a new empty (unformatted) partition in the empty space
- create and save checksums (sha256 or so) of every file in the filesystem
- using windows now, create an ntfs partition in the new partition
- crossing your fingers, on windows use ext2fsd to copy from the ext4 to the ntfs.
- using windows, create checksums of every file in the ntfs partition
- compare them and make sure nothing is fubar.
- assuming not, you can go back to ubuntu and delete the ext4 partition
- i don't know if windows give you a way to resize an NTFS partition (meaning resize the NTFS filesystem in the partition). if not, you'll have space left over.
Notice that #1, #5 and #9 are not without risk. Since you are not working with a backup, always a bad idea, I'll wish you good luck.