To scale below 100% was available as a feature in Windows 7 & 8,
but has been dropped in Windows 10. The interface provided by Windows
10 & 11 does not expose any such function.
The simplest way to zoom-out is to increase the screen resolution,
if it is available as an option by the display driver and the
display adapter, as long as you don't run into any limits.
If you have a separate graphic card that is not part of your CPU,
the software that comes with that card might provide this option.
For example, with a Nvidia GPU, the Nvidia Control Panel in the
"Manage 3D settings", scroll to "DSR - Factors", where DSR stands for
Dynamic Super Resolution. Here you can select factors of multiplication
to your current screen display resolution.
This can help, for example, if your current screen is limited to 1080p
but your monitor is 4K-capable.