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added 2 characters in body
Temani Afif
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To understand the why we need to perform some math.

If we start with the invert(1) (the easiest one) we will use f(x) = (255 - x)ref. So rgb(255,0,0) will become rgb(0,255,255)

For the hue-rotate(180deg) it's more complex. Considering the specification we will get the following matrix:

-0.574  1.43  0.144
 0.426  0.43  0.144
 0.426  1.43 -0.856

So we will have

R' =  -0.574*R  1.43*G  0.144*B = 1.43*255 + 0.144*255 = 401.37
G' =   0.426*R  0.43*G  0.144*B = 0.43*255 + 0.144*255 = 146.37
B' =   0.426*R  1.43*G -0.856*B = 1.43*255 - 0.856*255 = 146.37

Then a final color rgb(255,146.37,146.37) which is not a red one

html {
  background: rgb(255, 146.37, 146.37)
}


what can be done to use CSS to invert an image and still have red look like red?

It depends on what result you want to get considering the other colors but you can add a staturate() filter to get back your red color:

img {
 filter: invert(1) hue-rotate(180deg) saturate(10);
}
<img src="https://i.sstatic.net/jikdT.png">

Again some Math to understand what is happening. From the same specification and after some simplication we will have the following matrix:

 7.87  -7.15 -0.72
-2.13   2.85 -0.72
-2.13  -7.15  9.28

So

 R' =  7.87*R  -7.15*G -0.72*B =  7.87*255 - 7.87*146.37 = bigger than 255
 G' = -2.13*R   2.85*G -0.72*B = -2.13*255 + 2.13*146.37 = negative
 B' = -2.13*R  -7.15*G  9.28*B = -2.13*255 + 2.13*146.37 = negative

A final color rgb(255,0,0)

Temani Afif
  • 263.7k
  • 27
  • 345
  • 457