To find out what is letting your system hang you first need to drill down to the Windows hang. What was Windows doing while you did experience the hang?
To find this out you can take a kernel dump. How to get and analyze a Kernel Dump read here.
Depending on the findings you get there you then need to decide if there is anything under your control you can do about. Since you are using a third party library to to the writing there is little you can do except to set the IO priority, thread priority on thread or process level. If the library you were given links against a specific CRT you could try to build your own customized version of it to e.g. flush after every write to prevent write combining by the OS to write only data in big chunks back to disc.
Edit1
Your best bet would be to flush the device after every write. This could force the OS to flush any pending data and write the current pending writes to disc without caching the writes up to certain amount.
The second best thing would be to simply wait after each write to give the OS the chance to write pending changes though small back to disc after a certain time interval.
If you are deeper into performance you should try out XPerf which has a nice GUI and shows you even the call stack where your process did hang. The Windows Team and many other teams at MS use this tool to troubleshoot hang experiences. The latest edition with many more features comes with the Windows 8 SDK. But beware that Xperf only works on OS > Vista.