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I've used with success the following open source projects:
ExcelPackage for OOXML formats (Office 2007)
NPOI for .XLS format (Office 2003). NPOI 2.0 (AlphaBeta) also supports XLSX.
Take a look at my blog posts:
Creating Excel spreadsheets .XLS and .XLSX in C#
NPOI with Excel Table and dynamic Chart
NPOI for .XLS format (Office 2003). NPOI 2.0 (Alpha) also supports XLSX.
NPOI for .XLS format (Office 2003). NPOI 2.0 (Beta) also supports XLSX.
NPOI for .XLS format (Office 2003). NPOI 2.0NPOI 2.0 (Alpha) also supports XLSX.
Creating Excel spreadsheets .XLS and .XLSX in C#Creating Excel spreadsheets .XLS and .XLSX in C#
NPOI with Excel Table and dynamic ChartNPOI with Excel Table and dynamic Chart
NPOI for .XLS format (Office 2003)