In addition to other fine, more specific answer - I'll give a more general, and controvertial answer: Probably about every other episode of Star Trek TNG and Star Trek DS9; and that's because Star Fleet are bad guys.
No, I don't mean in the Mirror Universe (which could also serve as somewhat of an answer to your question) - I mean the regular one.
You see, Star Trek as a show is mostly a self-narrative of the United Federation of Planets, or rather of specific crews of ships or bases within Star Fleet. It's true that the show is written by real people on Earth in the 20th century CE, but they are choosing protagonists for their stories and describing them, or self-describing them, as the good guys. Unfortunately, that kind of flies in the face of facts (facts-in-the-universe-of-the-show of course).
I won't go into an entire dissertation of why the UFP is an evil empire, but in a nutshell:
- Human-supremacist civilization
- Privileged populations (e.g. on Earth) live lives of luxury and leisure while on most planets people need to work to make a living
- Huge parts of civilizational activity militarized fully or mostly: Foreign relations & diplomacy, scientific research, interstellar travel
- Civilian political structure flimsy and of little consequence, exerting no control over the military which effectively holds sovereignty
- Somewhat expansionistic
Point (5.) is actually the more difficult to demonstrate and argue for, but it's certainly the case if you look at Bajor. Even though supposedly that's not a planet which meets the criteria for entering the federation, it manages to strong-arm the Bajorans into letting it control a choke point for interstellar travel and commerce, by a military governor, with that governor also heavily interfering with Bajoran politics and religion. The Federation acts with the clear intent to take over Bajor, in the practical interstellar sense even if not formally through federation membership (which, recall, means loose subservience to Humanity and Earth).
You may want to check out this article about how the Federation is an evil empire (which not exactly my view, but somewhat close).