the number which Collatz transforms to them iseither they give a prime, thus can't be part of that square. number in the pre-Collatz graph ($70=3(23)+1$, $130=3(43)+1$, $220=3(73)+1$, $238=3(79)+1$) or they give a prime factor which is too large ($280=3(3\times31)+1$, etc.something else in the pre-Collatz graph must be a multiple of $31$ which is impossible).
we get the final answer.
How about uniqueness?
We had three remaining possibilities that might work as the central number in the post-Collatz graph. Now we know
154 does work; what about 190 and 286?
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$286=2\times11\times13$ is the Collatz transform of $95=5\times19$. The other multiple of 19 in the pre-Collatz graph must be $3\times19=57$, which Collatz transforms to $172=2^2\times43$. Then the post-Collatz graph is $286$, $172$, a multiple of 11, and a multiple of 13. But one of those last two must also be a multiple of 5, and both $5\times11=55$ and $5\times13=65$ are too big to be Collatz transforms of even numbers less than 100. Contradiction.
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$190=2\times5\times19$ is the Collatz transform of $63=3^2\times7$. The post-Collatz graph then must contain the number $19$, corresponding to $38=2\times19$ in the pre-Collatz graph. One of the remaining numbers in the pre-Collatz graph must be $3\times19=57$, which Collatz transforms to $172=2^2\times43$. Then the final number must be $2\times5\times7=70$ pre-Collatz and $5\times7=35$ post-Collatz.
So there is a second possibility, namely Freddy is
38
and the four mathematicians' ages are
38, 57, 63, 70 ($38=2\times19$, $57=3\times19$, $63=3^2\times7$, $70=2\times5\times7$)
with their Collatz-transformed ages being respectively
19, 172, 190, 35 ($19=19$, $172=2^2\times43$, $190=2\times5\times19$, $35=5\times7$).