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Covers the study of (primarily homogeneous) macroscopic systems from a heat/energy/entropy point of view. Consider also using the tag: [statistical-mechanics].
2
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1
answer
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Clearing up concepts regarding quasi-static processes
I have two main questions/problems:
Most definitions I've seen about quasi-static processes talk about them being "infinitely slow processes", or "slow enough as for the system to remain infinitesima …
10
votes
5
answers
4k
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Is there a "fundamental problem of thermodynamics"?
But is there such a thing for thermodynamics? Is there a formulation that allows for this kind of perspective? …
0
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1
answer
71
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Why does this assumption result in the correct answer to this problem?
The problem is the following: given the equation $u(s,v)=\frac{A}{v^2}e^{s/R} $ that governs a system that undergoes an isoentropic process $(T_i,p_i) \rightarrow \ (T_f,p_f)$ such that $p_f=p_i/2$, c …
0
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Heat capacity at constant volume Paradox
This is a common problem. The answer is that the Carnot cycle works for an ideal gas, and for an ideal gas it is always true that:
$$\Delta U = c_v n \Delta T $$
Yes, even if the process is not happen …
1
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Heating an object with black body radiation to above the temperature of the source
Filtering longer wavelengths will not make the spectrum equivalent to one of a hotter object. You'll simply be cutting out the region where the colder object peaks and leaving the tails that have a fa …
0
votes
1
answer
46
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Why does temperature remain constant in this case?
Consider two ideal gases of differing heat capacities. They occupy separate compartments of the same total volume. Assume their initial temperatures and that the amount of substance for both are the s …
0
votes
1
answer
56
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Doesn't the thermodynamic definition of temperature imply the existence of exotic systems wi...
The thermodynamic definition of temperature is simply:
$$T=\left(\frac{\partial{U}}{\partial{S}} \right)_{V,\ n}$$
As you see there is no absolute value involved. This implies that the partial derivat …
0
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Is a thermodynamic state variable the same as a Thermodynamic propertie and vice versa?
A thermodynamic property, let's call it $X$, might also have an equivalent state variable that can be used alongside other state variables to describe the equilibrium states of some system. However, t …
0
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1
answer
31
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Why isn't the Boltzmann factor the inverse of what it is defined as?
Let me explain a bit more what I mean. To derive the Boltzmann factor, one usually talks about the ratio of the probability that a system is at some specified energies $E_1$ and $E_2$. This is taken a …
3
votes
2
answers
626
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How can both of these equations for pressure be correct?
Consider the Gibbs equation:
$$du=Tds-pdv$$
Identifying partial derivatives, one obtains:
$$-p=\left( \frac{\partial u}{\partial v} \right)_T$$
But you can also show that:
$$p=T\left( \frac{\partial s …
1
vote
Accepted
How does thermodynamical entropy change when I let a gas flow out of a box?
What you called $S_1$ is really:
$$S_1 = S_1 (U,V,n) + K_1 $$
Where $K_1$ is the additive constant. The variation would be:
$$\Delta S = S_1(U_f,V_f,n_f)+K_1-S_1(U_i,V_i,n_i)-K_1=S_1(U_f,V_f,n_f)-S_1( …
0
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1
answer
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Is an isoentropic process also closed?
I'm trying to solve a problem where I'm asked to determine the $T_f/T_i$ ratio of an isoentropic expansion for a system with a particular $u(v,s)$ function. I have found a correct solution but at the …
0
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0
answers
60
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Can you find a better argument for this result in a thermodynamics problem?
Imagine two systems, A and B, both containing the same ideal gas and connected through a small tube such that they can interchange particles. They start out at $p_i$ and $T_i=T_A$, which for system A …
0
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0
answers
34
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How do I determine the relationship between initial and final volume in this case?
Some total volume contains two compartments separated by a wall that allows for mechanical and thermal interaction, each compartment having a different amount of an ideal gas. For the initial conditio …
1
vote
2
answers
194
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Is vapor pressure conserved during an adiabatic ascent of an air parcel?
Consider an air parcel with relative humidity $H$ and vapor pressure $e$ that experiments an adiabatic lifting process. Obviously the saturating vapor pressure is going to change since said process is …