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0 votes
1 answer
28 views

Why escape peak positions are calculated using emission energy and not absorbing energy?

For a X-ray monocromatic source, escape peaks energy positions are described by the difference between the incident energy and the fluorescence ($K_{\alpha}$ for example), like $E_{Escape Peak} = E_0 -...
xor's user avatar
  • 1
0 votes
1 answer
66 views

Convolution or addition? Proper way to model overlapping absorption line profiles

Suppose you obtain a measured spectral line shape (let's call it 'envelope') which appears as a skewed/asymmetric voigt profile. You know physically that the envelope line profile has this skew ...
kl_physicist's user avatar
4 votes
2 answers
1k views

Do atoms emit and absorb photons at the same wavelengths?

I know that atoms absorb photons, which promotes electrons to higher energy levels. Then upon de-excitation a photon is released. Is it true that the lines for absorption and emission spectrums are ...
theta's user avatar
  • 160
0 votes
0 answers
32 views

Reconciling two descriptions of fluorescence

I am currently studying the textbook Infrared and Raman Spectroscopy: Principles and Spectral Interpretation, second edition, by Peter J. Larkin. Section 9. Selecting the Raman Excitation Wavelength, ...
The Pointer's user avatar
1 vote
1 answer
62 views

fluorescence wavelength limit

My understanding is that fluorescence occurs when light has sufficient energy to excite an electron, which then emits a different photon (always with a larger wavelength) and releases the energy it ...
Kagekiba's user avatar
1 vote
0 answers
66 views

What are some mechanisms that can lead to unexpected/anomalous spectral lines

I am studying fluorescent spectroscopy (laser-induced fluorescence spectroscopy specifically). In a particular atomic spectrum, there are some unexpected lines not associated with any known ...
peasqueeze's user avatar
1 vote
1 answer
101 views

Two-photon absorption fluorescence of air

I'm wondering if there are any major constituents of air which are capable of undergoing two-photon absorption and ultimately fluorescing in the visible spectrum. The original wavelengths of the ...
G. Smith's user avatar