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  • $\begingroup$ I am not asking when the system reaches equilibrium. I am asking if we can measure the thermodynamic variables when the system hasn't reached equilibrium (when the rates are not equal). I will edit the post because I may confused you. I apologise. $\endgroup$ Commented Oct 15, 2020 at 16:22
  • $\begingroup$ OK, let me know when it is edited. $\endgroup$
    – Bob D
    Commented Oct 15, 2020 at 16:24
  • $\begingroup$ Ok I edited. To avoid writing on comments we can continue on chat if you want. $\endgroup$ Commented Oct 15, 2020 at 16:35
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    $\begingroup$ @AntoniosSarikas Thanks for the invite, but since your question seems to deal with the subject of non equilibrium thermodynamics, which I am not familiar with, I'll pass. Good luck. $\endgroup$
    – Bob D
    Commented Oct 15, 2020 at 20:56