Aluminium monofluoride: Difference between revisions
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| Name = |
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| IUPACName = Aluminium monofluoride |
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| ImageFile = Fluoridoaluminium-3D-vdW.png |
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| IUPACName = Fluoridoaluminium |
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| Abbreviations = |
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<!-- InChI and InChIKey do not match / June 2015 --> |
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| InChIKey = RSCDSAGMXGBEFR-REWHXWOFAJ |
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| InChI1 = 1/Al.3FH/h;3*1H/q+3;;;/p-3 |
| InChI1 = 1/Al.3FH/h;3*1H/q+3;;;/p-3 |
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| InChIKey1 = KLZUFWVZNOTSEM-DFZHHIFOAC |
| InChIKey1 = KLZUFWVZNOTSEM-DFZHHIFOAC |
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| InChIKey = APURLPHDHPNUFL-GBQYYLROAD |
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| CASNo_Ref = {{cascite|correct|??}} |
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| CASNo = 13595-82-9 |
| CASNo = 13595-82-9 |
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| ChemSpiderID_Ref = {{chemspidercite| |
| ChemSpiderID_Ref = {{chemspidercite||chemspider}} |
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| StdInChI_Ref = {{stdinchicite| |
| StdInChI_Ref = {{stdinchicite||chemspider}} |
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| SMILES = [Al+3].[F-] |
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| KEGG_Ref = {{keggcite|correct|kegg}} |
| KEGG_Ref = {{keggcite|correct|kegg}} |
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| KEGG = |
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| Al=1 | F=1 |
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| MolarMass = 45.98 g/mol |
| MolarMass = 45.98 g/mol |
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| Dipole = }} |
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| Section3 = {{Chembox Structure |
| Section3 = {{Chembox Structure |
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| Section4 = {{Chembox Thermochemistry |
| Section4 = {{Chembox Thermochemistry |
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| DeltaHf = |
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| REFactor = }} |
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| Section7 = {{Chembox Hazards |
| Section7 = {{Chembox Hazards |
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| NFPA-H = |
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| NFPA-F = |
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| PEL = }} |
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| Section8 = {{Chembox Related |
| Section8 = {{Chembox Related |
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| OtherAnions = [[aluminium monochloride]] |
| OtherAnions = [[aluminium monochloride]] |
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| OtherCations = [[lithium fluoride]], [[sodium fluoride]], [[potassium fluoride]] |
| OtherCations = [[lithium fluoride]], [[sodium fluoride]], [[potassium fluoride]] |
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'''Aluminium monofluoride''' is the [[chemical |
'''Aluminium monofluoride''' is the [[chemical ]] with the [[chemical formula|formula]] AlF. This elusive species is formed by the reaction between [[aluminium fluoride|aluminium trifluoride]] and metallic aluminium at elevated temperatures but quickly reverts to the reactants when cooled.<ref>{{cite journal | last1 = Dyke | first1 = C.Kirby | last2 = Morris | first2 = B.W.J.Gravenor | year = 1984 | title = A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy | journal = Chemical Physics | volume = 88 | issue = 2| page = 289 | doi = 10.1016/0301-0104(84)85286-6 }}</ref> Clusters derived from related aluminium(I) halides can be stabilized using specialized [[ligand]]s.<ref>{{cite journal | last1 = Dohmeier | first1 = C. | last2 = Loos | first2 = D. | last3 = Schnöckel | first3 = H. | year = 1996 | title = Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions | journal = Angewandte Chemie International Edition in English | volume = 35 | issue = 2| pages = 129–149 | doi = 10.1002/anie.199601291 }}</ref> |
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This molecule has been detected in the [[interstellar medium]], where molecules are so dilute that intermolecular [[collision theory|collisions]] are unimportant.<ref>{{cite journal | |
This molecule has been detected in the [[interstellar medium]], where molecules are so dilute that intermolecular [[collision theory|collisions]] are unimportant.<ref>{{cite journal |=L. M. Ziurys A. J. Apponi T. G. Phillips | title=Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF | journal=Astrophysical Journal | year=1994 | volume=433 | issue=2 | pages=729–732 | bibcode=1994ApJ...433..729Z | doi=10.1086/174682 }}</ref> |
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==See also== |
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*[[Aluminium monobromide]] |
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*[[Aluminium monochloride]] |
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==References== |
==References== |
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{{reflist}} |
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<references /> |
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{{Aluminium compounds}} |
{{Aluminium compounds}} |
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{{Fluorides}} |
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{{Molecules detected in outer space}} |
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[[Category:Aluminium(I) compounds]] |
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[[Category:Fluorides]] |
[[Category:Fluorides]] |
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[[Category:Metal halides]] |
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[[zh:一氟化铝]] |
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