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Aluminium monofluoride: Difference between revisions

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{{chembox
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| Verifiedfields = changed
| verifiedrevid = 443381187
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| ImageFile =
| verifiedrevid =
| ImageSize =
| Name =
| IUPACName = Aluminium monofluoride
| ImageFile = Fluoridoaluminium-3D-vdW.png
| OtherNames =
| ImageSize =
| Section1 = {{Chembox Identifiers
| IUPACName = Fluoridoaluminium
| OtherNames =
| SystematicName =
| Section1 = {{Chembox Identifiers
| Abbreviations =
| Abbreviations =
<!-- InChI and InChIKey do not match / June 2015 -->
| InChIKey = RSCDSAGMXGBEFR-REWHXWOFAJ
| InChI1 = 1/Al.3FH/h;3*1H/q+3;;;/p-3
| InChI1 = 1/Al.3FH/h;3*1H/q+3;;;/p-3
| InChIKey1 = KLZUFWVZNOTSEM-DFZHHIFOAC
| InChIKey1 = KLZUFWVZNOTSEM-DFZHHIFOAC
| InChI = 1/Al.FH/h;1H/q+;/p-1
| SMILES1 = F[Al](F)F
| InChIKey = APURLPHDHPNUFL-GBQYYLROAD
| StdInChI = 1S/Al./h;1H/q+;/p-
| StdInChIKey = -UHFFFAOYSA-
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 13595-82-9
| CASNo = 13595-82-9
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID_Ref = {{chemspidercite||chemspider}}
| ChemSpiderID = 2039
| ChemSpiderID =
| EINECS =
| EINECS =
| PubChem =
| PubChem =
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI_Ref = {{stdinchicite||chemspider}}
| StdInChIKey_Ref = {{stdinchicite||chemspider}}
| StdInChI = 1S/Al.3FH/h;3*1H/q+3;;;/p-3
| = F[Al]
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = KLZUFWVZNOTSEM-UHFFFAOYSA-K
| SMILES = [Al+3].[F-]
| InChI = 1/Al.FH/h;1H/q+3;/p-1
| RTECS =
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| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG_Ref = {{keggcite|correct|kegg}}
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| ATCCode_prefix =
| Section2 = {{Chembox Properties
| ATCCode_suffix =
| Formula =
| ATC_Supplemental =}}
| Al=1 | F=1
| Section2 = {{Chembox Properties
| Formula = AlF
| MolarMass = 45.98 g/mol
| MolarMass = 45.98 g/mol
| Appearance =
| Appearance =
| Density =
| Density =
| MeltingPt =
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| Melting_notes =
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| Dipole = }}
| Section3 = {{Chembox Structure
| Section3 = {{Chembox Structure
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| Section4 = {{Chembox Thermochemistry
| Section4 = {{Chembox Thermochemistry
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| Section5 = {{Chembox Pharmacology
| Section5
| Section6 = {{Chembox Explosive
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| Section6 = {{Chembox Explosive
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| Section7 = {{Chembox Hazards
| Section7 = {{Chembox Hazards
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| =
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| Section8 = {{Chembox Related
| Section8 = {{Chembox Related
| OtherAnions = [[aluminium monochloride]]
| OtherAnions = [[aluminium monochloride]]
| OtherCations = [[lithium fluoride]], [[sodium fluoride]], [[potassium fluoride]]
| OtherCations = [[lithium fluoride]], [[sodium fluoride]], [[potassium fluoride]]
| OtherFunctn =
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}}
}}
'''Aluminium monofluoride''' is the [[chemical substance]] with the [[chemical formula|formula]] AlF. This elusive species is formed by the reaction between [[aluminium fluoride|aluminium trifluoride]] and metallic aluminium at elevated temperatures but quickly reverts back to the reactants when cooled.<ref>{{cite journal | last1 = Dyke | first1 = C.Kirby | last2 = Morris | first2 = B.W.J.Gravenor | year = 1984 | title = A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy | url = | journal = Chemical Physics | volume = 88 | issue = 2| page = 289 | doi = 10.1016/0301-0104(84)85286-6 }}</ref> Clusters of derived from related aluminium(I) halides can be stabilized using specialized [[ligand]]s.<ref>{{cite journal | last1 = Dohmeier | first1 = C. | last2 = Loos | first2 = D. | last3 = Schnöckel | first3 = H. | year = 1996 | title = Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions | url = | journal = Angewandte Chemie International Edition in English | volume = 35 | issue = 2| pages = 129–149 | doi = 10.1002/anie.199601291 }}</ref>
'''Aluminium monofluoride''' is the [[chemical ]] with the [[chemical formula|formula]] AlF. This elusive species is formed by the reaction between [[aluminium fluoride|aluminium trifluoride]] and metallic aluminium at elevated temperatures but quickly reverts to the reactants when cooled.<ref>{{cite journal | last1 = Dyke | first1 = C.Kirby | last2 = Morris | first2 = B.W.J.Gravenor | year = 1984 | title = A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy | journal = Chemical Physics | volume = 88 | issue = 2| page = 289 | doi = 10.1016/0301-0104(84)85286-6 }}</ref> Clusters derived from related aluminium(I) halides can be stabilized using specialized [[ligand]]s.<ref>{{cite journal | last1 = Dohmeier | first1 = C. | last2 = Loos | first2 = D. | last3 = Schnöckel | first3 = H. | year = 1996 | title = Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions | journal = Angewandte Chemie International Edition in English | volume = 35 | issue = 2| pages = 129–149 | doi = 10.1002/anie.199601291 }}</ref>


This molecule has been detected in the [[interstellar medium]], where molecules are so dilute that intermolecular [[collision theory|collisions]] are unimportant.<ref>{{cite journal | author=L. M. Ziurys, A. J. Apponi, T. G. Phillips | title=Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF | journal=Astrophysical Journal | year=1994 | volume=433 | issue=2 | pages=729–732 | bibcode=1994ApJ...433..729Z | doi=10.1086/174682 }}</ref>
This molecule has been detected in the [[interstellar medium]], where molecules are so dilute that intermolecular [[collision theory|collisions]] are unimportant.<ref>{{cite journal |=L. M. Ziurys A. J. Apponi T. G. Phillips | title=Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF | journal=Astrophysical Journal | year=1994 | volume=433 | issue=2 | pages=729–732 | bibcode=1994ApJ...433..729Z | doi=10.1086/174682 }}</ref>

==See also==
*[[Aluminium monobromide]]
*[[Aluminium monochloride]]
[[Aluminium ]]


==References==
==References==
{{reflist}}
<references />


{{Aluminium compounds}}
{{Aluminium compounds}}
{{Fluorides}}
{{inorganic-compound-stub}}
{{Molecules detected in outer space}}
[[Category:Aluminium compounds]]

[[Category:Aluminium(I) compounds]]
[[Category:Fluorides]]
[[Category:Fluorides]]
[[Category:Metal halides]]



[[zh:一氟化铝]]
{{inorganic-compound-stub}}