All Questions
7
questions
0
votes
0
answers
102
views
Jahn-Teller Distortion: How to compare magnitudes (in Cu2+ complexes)?
Octahedral complex of copper(II) undergo structural distortion (Jahn-Teller). Which one of the given copper(II) complexes will who the maximum structural distortion? (en - ethylenediamine)
(A) $[Cu(...
6
votes
2
answers
638
views
Chromium cyanide complexes
I have rarely seen any chromium $(\ce{Cr})$ square planar complexes and I have been told that $\ce{[Cr(CN)4]-}$ is tetrahedral.
So, if the statement is actually correct, are there any other known ...
- 333
2
votes
1
answer
739
views
ligand pi system irreducible representation for trigonal bipyramidal transition metal complex
I am considering a D$_{3h}$ trigonal bipyramidal transition metal complex MX$_5$. I have found that the irreducible representation for the ligand s and $\sigma$ systems is 2A$_1'$+A$_2''$+E$'$. I ...
- 353
1
vote
0
answers
782
views
Does Ni(H2O)6 have Oh symmetry or Th?
I optimized a geometry of $\ce{Ni(H2O)6}$ using quantum chemistry and got a molecule which is symmetrical for the $\ce{Ni-O}$ distances as shown
here:
In the literature it says that this complex has ...
- 9
12
votes
1
answer
16k
views
Derivation of the Orgel diagram for octahedral d2 complexes
The Orgel diagram for a typical octahedral $\mathrm{d^2}$ complex is shown below:
(source: Kettle, Physical Inorganic Chemistry, p 146)
I understand that the right-hand half of the graph shows how ...
- 71.6k
10
votes
1
answer
41k
views
How do I find the ground state term symbol for transition metal complexes?
I have a problem where I'm trying to match metal complexes with the proper ground state term symbol. I've tried doing a Google search and looking for a process, but haven't had any luck. I decided ...
- 355
2
votes
1
answer
667
views
Orbital mixing in square planar D4h complexes
Consider a square planar $\ce{ML4}$ complex with $D_\mathrm{4h}$ symmetry. Which orbital should the $\mathrm{a_{1g}}$ SALC of the ligands mix with, $\mathrm{3d}_{z^2}$ or $\mathrm{4s}$? Both of those ...
- 21