Questions tagged [stereoelectronics]
For questions where the reactivity/conformation of the molecule is defined/controlled by a specific orbital arrangement/alignment (for example the unusual conformation of sugars because of the anomeric effect). This tag cannot be the only tag on a question. Tags such as [conformation] and [torganic-chemistry] must also be applied.
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Why do the dipoles in dichloroethane point in opposite directions?
I understand why the dipoles would align in a polar solvent to maximise dipole-dipole interactions but wouldn't the replulsion due to like charges destabilise the molecule? Is it a MO effect instead? ...