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Questions tagged [intramolecular-reaction]

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-4 votes
1 answer
58 views

Decomposition Redox Rxn Vs. Intramolecular Redox Rxn

I'm trying to understand what is the difference between decomposition redox reaction and intramolecular redox reaction? Are they synonymous? Is there a reaction which belongs to one but not the other ...
Apogee Point's user avatar
6 votes
1 answer
448 views

Using Thionyl Chloride with tertiary alcohol

I have a question regarding using $\ce{SOCl2}$ to convert an alcohol into a alkyl halide. The Klein book mentions that $\ce{SOCl2}$ is only used for primary and secondary alcohol; however, in the ...
Jaehyun Ahn's user avatar
0 votes
0 answers
887 views

What mechanism do reaction of PCl5 follows, SNi or SN2?

I was taught that $\ce{PCl5}$ reacts with alcohols by $S_Ni$ mechanism as shown below: Here it can be seen that $\ce{PCl5}$ exists as $\ce{[PCl4]+[PCl6]-}$ and so lone pair of the alcohol is donated ...
D13G's user avatar
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