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3 votes
1 answer
2k views

How does the entropic force arise within the hydrophobic effect?

I know that the hydrophobic effect is usually explained by the entropic effect originating from the disruption of hydrogen bonds between molecules of water and the nonpolar substance. The hydrogen ...
Treex's user avatar
  • 153
7 votes
1 answer
3k views

Specific Heat Capacity of Heavy Water

Water has an unusually high specific heat capacity due to it's hydrogen bonds. Why is it that the change in isotope causes a 10% difference in the heat capacity? How does the added neutron in the ...
Tethys's user avatar
  • 109
24 votes
5 answers
67k views

Why does hydrogen fluoride have a boiling point so much lower than that of water?

$\ce{F}$ has more unshared electron pairs and is very electronegative, so $\ce{H}$ of another $\ce{HF}$ molecule can $\ce{H}$-bond with it. $\ce{HF}$ has normal boiling point of $\pu{19.5^oC}$ while $...
Acnologia's user avatar
  • 819