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12 votes
2 answers
2k views

Why hydrogen bonding in some acids make them a stronger acid when it is present even before deprotonation?

If we take the example of salicylic acid, hydrogen bonding is present in the acid as follows: Even after deprotonation, it has intramolecular hydrogen bonding as follows: My question: p-...
Neha's user avatar
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7 votes
0 answers
1k views

Steric inhibition of resonance vs. hydrogen bonding

I have to compare the acidic strength of these compounds: Now, in A and B hydrogen bonding will be present which will help stabilize the negative charge of the conjugate base. However, the hydroxyl ...
xasthor's user avatar
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