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-2 votes
2 answers
289 views

What is the reason for extracting copper from copper pyrites and not iron?

Why can copper be extracted from copper pyrites ($\ce{CuFeS2}$) but not iron? Is there some intuitive logic behind it?
Abhiram Cherukupalli's user avatar
1 vote
2 answers
1k views

Extraction of copper from chalcopyrite

During the extraction of copper from chalcopyrite ore, the ore ($\ce{Cu2S.Fe2S3}$) is heated to form $\ce{Cu2S}$ and $\ce{FeS}$. Then during smelting it reacts with $\ce{O2}$ to form $\ce{Cu2O}$. Then ...
Siddhartha Mondal's user avatar
2 votes
0 answers
95 views

Why does 'softening' of lead oxidise only elements other than lead?

In a flowchart describing the steps to refine lead obtained after the reduction step, my book1 gives a short note on the process 'Softening of lead' where the crude lead is melted in the presence of ...
Vishnu's user avatar
  • 2,090
0 votes
0 answers
254 views

Difference between calcination, roasting and pyrolysis

Hie everyone. I have been going through pyrometallurgical processes for recycling lithium-ion batteries and l have been coming across these terms; calcination, pyrolysis and roasting which l need ...
bryanmaks's user avatar
2 votes
1 answer
661 views

Use of Spiegeleisen in manufacture of steel

I recently read the following statements related to Manufacture of steel via Bessemer Process: When no more $\ce{CO}$ is produced (i.e. blue flame disappears) a calculated amount of Spiegeleisen (...
Zenix's user avatar
  • 1,350
8 votes
1 answer
631 views

Need of refining aluminium and Hoope vs Hall–Héroult processes

Recently I was taught how aluminium is commercially extracted. The ore is first concentrated by leaching either by Bayer's process for red bauxite (impurity: $\ce{Fe2O3}$) or by Serpeck's process for ...
Sir Arthur7's user avatar
  • 1,169
0 votes
0 answers
30 views

Separation of Al-Si alloys without electrolysis

Can pure (or roughly pure) $\ce{Al}$ be somehow thermally, chemically, or physically separated from the $\ce{Si}$ contained in an $\ce{Al-Si}$ alloy? How? Approximately what purity of Aluminum can be ...
R Dev's user avatar
  • 313
1 vote
1 answer
3k views

Why do we use coke instead of coal in order to reduce FeO as basic reaction in ironmaking process?

Why is coke used as a reducing agent to reduce FeO to produce iron instead of coal.I admit that coke is carbonaceous but what is it that compels us to use coke instead of the naturally available coal?
user586228's user avatar
7 votes
2 answers
6k views

Why is ZnO reduced in this reaction?

Consider the following Ellingham diagram. At 673K, the Gibbs energy value of oxidation of Zn is more negative than the Gibbs energy value of oxidation of C (coke). So, Zn should be oxidised to ZnO. ...
Siddharth Venu's user avatar
3 votes
1 answer
630 views

Zinc Sulfate Purification

In the process for electrolysis for zinc, three things must be done: Leaching the ZnO Purifying the ZnSO4 by means of cementation Performing the electrolysis However, step 2, as it is presented by ...
Eames's user avatar
  • 133
6 votes
2 answers
4k views

Froth floatation process - why CuSO4 is activating floating character of ZnS?

I read the following : "In a mixture of $\ce{PbS}$, $\ce{ZnS}$ and $\ce{FeS2}$, each component is separated from each other in froth floatation process by using the reagents potassium ethyl ...
Resorcinol's user avatar
  • 1,439
8 votes
3 answers
8k views

When is Serpeck's process preferred over Bayer's process?

Both these processes are used in concentration of bauxite. They use different reagents. Which is more commonly used (wikipedia says Bayer's) and why? When is one preferred over the other? Which is ...
Kim's user avatar
  • 97
18 votes
4 answers
3k views

What possibilities are there for refining aluminium on the moon?

Engines burning aluminium and liquid oxygen have been investigated for use on the moon because there is plenty of both elements in the soil - about 13% and 40% of highland soil, respectively. ...
kim holder's user avatar