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-1 votes
1 answer
130 views

Why is the ionic product of water also the equilibrium constant of dissociation of water?

This answer presents a derivation of the value of ionic product of water at $25^{\circ}\text{C}$. The relation $K_\text{eq} = \operatorname{e}^{-\frac{\Delta_\text{r}G^{\circ}}{RT}}$ is used for the ...
Dodo's user avatar
  • 288
-1 votes
1 answer
374 views

Why do we take active mass of water 1 but while calculating pKa of water as 55.345? [duplicate]

First, I should mention that the question was already asked here:Why is active mass of a pure solid or liquid always taken as unity? But while calculating $\mathrm{p}K_\mathrm{a}$ of pure water we ...
mATHSloVER's user avatar
8 votes
2 answers
2k views

Why does increasing the pressure cause ice to melt more?

This question was given under chemical equilibrium. Why does increasing the pressure on this system cause ice to melt more? $$\ce{H2O(s) <=> H2O(l)}$$ I'm pretty sure this has to be ...
Avyansh Katiyar's user avatar
4 votes
1 answer
31k views

Determining standard Gibbs free energy for water?

I am dealing with the dissociation of water into its components hydrogen and oxygen and I am trying to determine the standard Gibbs free energies of each component. My professor said if the substance ...
Greg Harrington's user avatar
25 votes
2 answers
13k views

Why does water dissociate to H3O+ and OH- rather than H+ and OH-?

Why does water dissociate to $\ce{H3O+ + OH-}$ instead of $\ce{H+ + OH-}$? This question came to surface when I was learning about acids and bases, and learned this definition: $\mathrm{pH=}-\log_{10}[...
Ell's user avatar
  • 383