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3 votes
2 answers
20k views

How to calculate Gibbs free energy from pKa?

Is it possible to calculate Gibbs free energy ($ΔG = -RT\ln K_\mathrm{eq}$) of an acid dissociation reaction using the $\mathrm{p}K_\mathrm{a}$? If so, how?
user43702's user avatar
1 vote
2 answers
991 views

Do catalysts shift equilibrium constant towards 1?

I want to be able to understand shifts in equilibrium from the maxwell boltzmann distribution. One thing I cannot get my head around is the effect of catalysts on the equilibrium position - supposedly ...
user avatar
2 votes
1 answer
2k views

Do catalysts increase the rate of exothermic reaction more in a reversible reaction?

I'm just learning chemistry for school and I've learnt that adding a catalyst reduces the activation energy for the forward and backward reaction by equal amounts, therefore the rate of forward and ...
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0 votes
1 answer
3k views

How to calculate the Gibbs free energy from the equilibrium constant for the decomposition of sodium bicarbonate?

Solid $\ce{NaHCO3}$ is heated to $90~^\circ\mathrm{C}$. At equilibrium the total pressure of the gases produced is $0.545~\mathrm{atm}$. Calculate $\Delta G^\circ$ at $90~^\circ\mathrm{C}$ for the ...
twrightsman's user avatar