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0 votes
0 answers
35 views

Relative magnitude of the crystal field and spin-orbit coupling

In the EPR part of the book 'Physical methods in Inorganic Chemistry' by S. Drago i found that relative magnitudes of crystal field and spin-orbit coupling affect the g values. I understand that the ...
Chemistry.'s user avatar
3 votes
1 answer
159 views

Assigning structure based on EPR spectroscopy

When given two copper(II) complexes - bis(N-3-chlorophenyl-salicydenaminato)copper(II) and bis(N-3-methylphenyl-salicydenaminato)copper(II) - how can you predict their EPR spectrum and hence their g ...
qwerty09's user avatar
1 vote
0 answers
88 views

Can % location of electron on metal or ligand be negative (EPR)?

Given an EPR spectrum of [Co(3-methoxysalen)(py)] : and equations: A(x) = A(iso) + B A(z) = A(iso) - 2B %Co in SOMO = B/B0 where A(x) and A(z) are hyperfine coupling constants measured from the ...
Luna's user avatar
  • 11
4 votes
1 answer
767 views

Factors to consider to predict EPR

What are the factors to consider when predicting the EPR spectrum of $\ce{Cu(Ox)P(CH3)3}$ where $\ce{OX}$ is the oxalate ion? I understand that there are several factors to consider for EPR (Electron ...
Kinformationist's user avatar